Thermophysical properties: binary diffusion coefficients at 1 atm
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Substance A | Substance B | T(K) | DAB (m2/s) | |
Gases | NH3 | Air | 298 | 0.28 × 10-4 |
H2O | Air | 298 | 0.26 × 10-4 | |
CO2 | Air | 298 | 0.16 × 10-4 | |
H2 | Air | 298 | 0.41 × 10-4 | |
O2 | Air | 298 | 0.21 × 10-4 | |
Acetone | Air | 273 | 0.11 × 10-4 | |
Benzene | Air | 298 | 0.88 × 10-5 | |
Naphthalene | Air | 300 | 0.62 × 10-5 | |
Ar | N2 | 293 | 0.19 × 10-4 | |
H2 | O2 | 273 | 0.70 × 10-4 | |
H2 | N2 | 273 | 0.68 × 10-4 | |
H2 | CO2 | 273 | 0.55 × 10-4 | |
CO2 | N2 | 293 | 0.16 × 10-4 | |
CO2 | O2 | 273 | 0.14 × 10-4 | |
O2 | N2 | 273 | 0.18 × 10-4 | |
Dilute solutions | Caffeine | H2O | 298 | 0.63 × 10-9 |
Ethanol | H2O | 298 | 0.12 × 10-8 | |
Glucose | H2O | 298 | 0.69 × 10-9 | |
Glycerol | H2O | 298 | 0.94 × 10-9 | |
Acetone | H2O | 298 | 0.13 × 10-8 | |
CO2 | H2O | 298 | 0.20 × 10-8 | |
O2 | H2O | 298 | 0.24 × 10-8 | |
H2 | H2O | 298 | 0.63 × 10-8 | |
N2 | H2O | 298 | 0.26 × 10-8 | |
Solids | O2 | Rubber | 298 | 0.21 × 10-9 |
N2 | Rubber | 298 | 0.15 × 10-9 | |
CO2 | Rubber | 298 | 0.11 × 10-9 | |
He | SiO2 | 293 | 0.4 × 10-13 | |
H2 | Fe | 293 | 0.26 × 10-12 | |
Cd | Cu | 293 | 0.27 x 10-18 | |
Al | Cu | 293 | 0.13 x 10-33 | |
Assuming ideal gas behavior, the pressure and temperature dependence of the diffusion coefficient for a binary mixture of gases may be estimated form the relation DAB∝p-1T3/2
References
Faghri, A., and Zhang, Y., 2006, Transport Phenomena in Multiphase Systems, Elsevier, Burlington, MA.
Faghri, A., Zhang, Y., and Howell, J. R., 2010, Advanced Heat and Mass Transfer, Global Digital Press, Columbia, MO.